(R)-(-)-2-(9-FLUORENYLMETHOXYCARBONYL)-1,2,3,4-TETRAHYDRO-3-ISOQUINOLINECARBOXYLIC ACID
N-FMOC-D-1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid
CAS: 130309-33-0
Molecular Formula: C25H21NO4
(R)-(-)-2-(9-FLUORENYLMETHOXYCARBONYL)-1,2,3,4-TETRAHYDRO-3-ISOQUINOLINECARBOXYLIC ACID - Names and Identifiers
| Name | N-FMOC-D-1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid |
| Synonyms | Fmoc-D-Tic Fmoc-D-Tic-OH RARECHEM BK PT 0081 Fmoc-D-Tetrahydroisoquinoline-3-COOH N-FMOC-D-1,2,3,4-TETRAHYDROISOQUINOLINE-3-CARBOXYLIC ACID N-FMOC-D-1,2,3,4-Tetrahydroisoquinoline-3-carboxylic acid FMOC-(3R)-1,2,3,4-TETRAHYDROISOQUINOLINE-3-CARBOXYLIC ACID (R)-N-FMOC-1,2,3,4-TETRAHYDROISOQUINOLINE-3-CARBOXYLIC ACID N-1-FMOC-D-1,2,3,4-TETRAHYDRO-ISOQUINOLINE-3-CARBOXYLIC ACID N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-D-1,2,3,4-TETRAHYDROISOQUINOLINE-3-CARBOXYLIC ACID (R)-(-)-2-(9-FLUORENYLMETHOXYCARBONYL)-1,2,3,4-TETRAHYDRO-3-ISOQUINOLINECARBOXYLIC ACID N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-D-1,2,3,4-TETRAHYDROISOQUINOLINE-3-CARBOXYLIC ACID |
| CAS | 130309-33-0 |
| InChI | InChI=1/C25H21NO4/c27-24(28)23-13-16-7-1-2-8-17(16)14-26(23)25(29)30-15-22-20-11-5-3-9-18(20)19-10-4-6-12-21(19)22/h1-12,22-23H,13-15H2,(H,27,28)/p-1/t23-/m1/s1 |
| InChIKey | LIRBCUNCXDZOOU-HSZRJFAPSA-N |
(R)-(-)-2-(9-FLUORENYLMETHOXYCARBONYL)-1,2,3,4-TETRAHYDRO-3-ISOQUINOLINECARBOXYLIC ACID - Physico-chemical Properties
| Molecular Formula | C25H21NO4 |
| Molar Mass | 399.44 |
| Density | 1.2390 (rough estimate) |
| Melting Point | 160-164 °C |
| Boling Point | 522.37°C (rough estimate) |
| Flash Point | 334.7°C |
| Vapor Presure | 9.86E-17mmHg at 25°C |
| Appearance | White crystalline powder |
| pKa | 3.82±0.20(Predicted) |
| Storage Condition | Sealed in dry,Store in freezer, under -20°C |
| Refractive Index | 1.6000 (estimate) |
| MDL | MFCD00144345 |
(R)-(-)-2-(9-FLUORENYLMETHOXYCARBONYL)-1,2,3,4-TETRAHYDRO-3-ISOQUINOLINECARBOXYLIC ACID - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Safety Description | 24/25 - Avoid contact with skin and eyes. |
| WGK Germany | 3 |
| HS Code | 29334900 |
| Hazard Class | IRRITANT |
(R)-(-)-2-(9-FLUORENYLMETHOXYCARBONYL)-1,2,3,4-TETRAHYDRO-3-ISOQUINOLINECARBOXYLIC ACID - Introduction
Nature:
N-Fmoc-D-1,2,3, 4-tetrahydroisoquinoline-3-carboxylic acid is a white solid. It is relatively stable at room temperature and can be well dissolved in solvents. It is a compound with a certain chirality.
Use:
N-Fmoc-D-1,2,3, 4-tetrahydroisoquinoline-3-carboxylic acid is a common intermediate in organic synthesis. It can be used in peptide synthesis, drug research and other fields. Its chiral structure determines its special role in the synthesis of biologically active molecules.
Preparation Method:
N-Fmoc-D-1, the synthesis of 2,3, 4-tetrahydroisoquinoline-3-carboxylic acid is usually completed by a multi-step reaction. A common method of preparation is the esterification of D-1,2,3, 4-tetrahydroisoquinoline with Fmoc-Cl. The specific synthetic steps need to be carried out in a chemical laboratory.
Safety Information:
N-Fmoc-D-1,2,3, 4-tetrahydroisoquinoline-3-carboxylic acid is relatively safe under general operating conditions, but safety measures still need to be paid attention to during use and handling. It may be irritating to the eyes, skin and respiratory tract and direct contact should be avoided. When used in the laboratory, personal protective equipment such as protective gloves, goggles and protective clothing should be worn.
Last Update：2024-04-09 02:00:41
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View History
(R)-(-)-2-(9-FLUORENYLMETHOXYCARBONYL)-1,2,3,4-TETRAHYDRO-3-ISOQUINOLINECARBOXYLIC ACID
PROPYLENE, ISOTACTIC RESIN
PROPYLENE, ISOTACTIC RESIN